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Lime only works properly IN the soil where it's sitting there preventing the acidity in the peat from becoming the dominant factor in soil pH, and feeding calcium to the plants, UNTIL IT IS USED UP. This happens in 4-8 weeks from first wetting, depending on a lot of factors. It is also a weak base, not a strong base, and you need a LOT more to neutralize acid.
pH up is a strong base, that dissociates into the metal ion (sodium, potassium, whatever you are using) plus a free -OH that can combine with the hydronium ions that are your functional acid in the solution, and neutralize them, because H+ + OH- => H2O.
So you use lime to stabilize soil pH preventatively, and pH up to change it when you observe a problem.
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